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Thin films

Thin films

 

 

Thin films

THIN FILMS AND ION TECHNIQUES

1. Physical properties of thin films are different from the properties of bulk materials:

  • Electrical
  • Magnetic
  • Optical
  • Mechanical
  • Thermal, etc…

2. Substrate and its influence
3. Thickness dependence

Methods of deposition

  • PHYSICAL
    • Evaporation                  vapor
    • Sputtering                      vapor
    • Printing                           liquid
  • CHEMICAL
    • CVD                                               vapor
    • LPE                                 liquids
  • PHYSICO-CHEMICAL
    • Electroplating
    • Polymerization

2.1. Evaporation

Basic concept: melt the source and evaporate in vacuum.
Main problem: Interaction with residual gases (mean free path)

On the substrate:

K=Nd/Ng=thin films

Where: A - Avogadro number, r - specific mass of the deposit [g/m3], Md - molecular mass of the deposit, vdep - speed of deposition [A/s], p – pressure [Tr].

Example: Residual gas N2, deposit Al, vdep= 1A/s

K= 1.6*10-3 @ 10-4 Tr; 1.6*10-1 @ 10-6 Tr, 1.6 *101 @ 10-8 Tr

Realistic pressures require minimum deposition speed of the order of 10 A/s

 

Thickness distribution of a source

Mass evaporated in a unit time: thin films
Two models for describing real sources:

  • Isotropic source – point source : f(a) = const.
  • Planar source f(a) ~ cos a.

Real source – a mixture of a number of plain and point sources

In real systems the thickness distribution does not depend only on the source characteristics but also on the source-substrate geometry.

 

thin films

 

L1,L2, > L0

Averaging by rotation – see fig 21a

Sources

 

Resistive (fig 21 b)

  • Interaction between the source and the deposit
  • Wetting
  • Geometry
  • Sublimating materials

Electron beam sources

  • Electrostatic
  • Magnetic

Scanning sources
Needs careful cooling
X-ray emissions

Flash sources – flash evaporation
For materials with changing composition (eg 21 e)

Substrate cooling and heating

  • Resistive
  • Halogen lamp

Substrate preparation and cleaning

  • Mechanical
  • Chemical
  • AC glow discharge
  • Baking

2.2. Sputtering

Basic concept

 

  • DC and RF sputtering
  • Bias sputtering
  • Reactive sputtering
  • Chemical sputtering (ion etching)

 

thin films

Physical effects of ion bombardment on surfaces

 

  • Emission of neutral particles from the target.

The sputtering yield: the number of neutral particles emitted per an incident ion.
See table 1.

  • Emission of other particles
  1. Secondary electrons.

The secondary electrons are accelerated away from the negative target with the energy of the target potential. They help to maintain the discharge. Many get thermalized but still many reach the substrate with the full energy.

  1. Secondary ions.

The basics of SIMS(secondary ion mass spectroscopy). Most of the SIMS data deals with positive ions. In sputtering, it is highly improbable that positive ions would escape the negative target field. The negative ions result from sputtering of anionic species of compounds and high electron affinity constituents of alloys. Negative ions are accelerated away from the target toward the substrate. Due to interactions in the gas plasma arrive to the substrate as highly energetic neutrals.
No negative ions while sputtering pure metals.

  1. Reflected incident particles.

The basic of ISS (ion scattering spectroscopy). One more source of substrate bombardment. These medium energy particles may be neutralized.

  1. Desorption of gases.

Leave the surface as negative ions – problems with porous targets.

  • Radiation emission due to sputtering.
  • UV and visible photons. Close to the target there are Auger-like electron transitions in the excited sputtered ions with subsequent emission of characteristic photons of the metal. These electronic transitions do not apply to dielectrics and compounds.
  • X-rays. Something capable of damaging the film.
  • Ion implantation.
  • Altered surface layers and diffusion.

While sputtering a multi-component target the composition of the surface changes due to a difference in the yield for various components. In the steady state the altered layer of a different composition from the bulk is formed. For metals the thickness of the altered layer is thin films, for oxides thin films.

Glow discharges

dc glow discharge

(see fig. on page 64)
Formation of the glow discharge under increasing power from the power supply in a form of a high impedance source- 
Insert fig p.64:

In subsequent steps one observes:

  • Small currents due to natural ionization (thermal, cosmic rays, etc)
  • More energy, current increases at a constant voltage due to the limit imposed by the output impedance of the power supply (“Townsend discharge”)
  • Avalanche effect (due to secondary electrons). Voltage increases, but the current increases much faster. - when the number of electrons is just enough to produce enough ions to regenerate the same number of electrons – the discharge becomes self-sustaining – “normal glow”. The current grows until the entire cathode surface is covered with the glow and there is a uniform current density. This regime was used in voltage regulator tubes.
  • When the whole cathode surface is covered, further increase in power results in increase of both voltage and current density in the discharge – “abnormal glow”. This is the regime, which is used in sputtering.
  • If the cathode is not cooled then at about J~0.1 A/cm2 thermionic electrons are added to the secondary ones, followed by a further avalanche. The output impedance of the power supply limits the voltage and a low voltage, high current arc discharge forms.

Crucial to the formation of an abnormal glow is the breakdown voltage, VB. VB depends on the mean free path of the secondary electrons and the distance dA-C between the anode and the cathode. Each secondary electron must produce 10 to 20 ions for the avalanche to occur. Paschen’s low describes the dependence of VB on the product thin films 

thin films

 

Zone I:
VB increases as thin films decreases, since there are not enough collisions.
Zone III:
VB increases with increasing thin films because due to many collisions the secondary electrons are too slow to ionize.

 

Most sputtering systems operate on the border between zone I and II. This requires relatively high discharge starting voltages.

Solutions:

  • ignition electrode
  • ignition gas burst
  • ignition instantaneous shortening of the A-C distance
  • additional source, e.g. Tesla coil

Luminous regions of dc glow discharge

 

(See Fig. 22a)

  • Adjacent to the cathode –cathodic glow (very brilliant). In this region secondary electrons start to accelerate and positive ions produced at the cathode are neutralized. The light is characteristic of both the cathode material and the incident ion (gas).
  • Secondary electrons at high velocities start to make collisions with neutral gas atoms at a distance away from the cathode corresponding to their mean free path. This leaves well-defined dark space. Since electrons rapidly loose their energy in collisions, almost all of the applied voltage appears across the dark space. Thus the darks space is the region in which positive ions are accelerated towards the cathode. The mobility of electrons is much higher than the mobility of ions, therefore, the predominant species in the dark space are ions.
  • The negative glow -- the region of ionizing collisions by accelerated secondary electrons.
  • Faraday dark and positive glow columns are nearly field free regions, solely connecting electrically the negative glow to the anode. Both regions are not essential to the operation of a glow discharge. In most systems the anode is located in the negative glow, and other regions do not exist.

The length of unobstructed negative glow corresponds to the range of electrons accelerated from the cathode. If the negative glow is truncated, higher voltages have to be applied to compensate for the ions that would be generated in the part blocked by the anode. In general for uniform operation the anode should be located at least 3 to 4 times the length of he cathode dark space (this distance is inversely proportional to the pressure)

ac and rf glow discharge

ac – typically up to 50kHz where ions are mobile enough to follow the voltage and form a dc like discharge on alternating both electrodes. When f >> 50kHz we deal with rf discharge where:

  • electrons that oscillate in the glow space acquire sufficient energy to cause ionizing collisions – lower breakdown voltage VB
  • Electrodes no longer need to be electrical conductors since rf voltage can be coupled through any type of impedance – possibility of sputtering dielectric materials!

How the sputtering occurs at all if ions at thin films are relatively immobile (typical thin films=13.56 MHz). The answer: when rf bias is capacitively coupled to the electrode, pulsating negative voltage develops on the cathode – sputtering effect.

Due to difference in mobilities of electrons and ions the I-V characteristics of a glow discharge resembles that of leaky rectifier.
(Insert fig. From page 70)

After the first cycle there is a difference in ion and electron current. Since no charge can be transferred through the capacitor the voltage on the electrode must self – bias it negatively until the net current (averaged over the cycle) is zero.

In order to sputter from the target only one couples the target via a capacitor to the generator, and the area of the capacitively coupled electrode must be small compared to the area of the dc-coupled electrode because:
thin films
thin films,- Voltage between the glow space and the capacitively coupled electrode.  thin films- area of the capacitively coupled electrode. thin films,thin films - voltage, area of the direct coupled electrode. To minimize the spurious sputtering from the dc coupled electrode Ad>>Ac is required. In practice the dc-coupled electrode is constituted by the system (chamber walls + baseplate), so the ratio is high.

The disstribution of the potential in the system : (insert  fig. on page 71)

Discharge support modes

 

  • axial magnetic field, perpendicular to the target surface
  • rf coil
  • thermoionic support – triode system

Ions generated in a low voltage (~50V), high current (5-20A) arc discharge between a thermoionic filament and a main anode. The target is located in the main discharge and ions are extracted from it toward the target that can be powered either by dc or rf source. Triode systems are mainly used for ion etching processes requiring large amounts of ions.

Equipment for sputtering

Schematic of an rf sputtering equipment – insert fig p.73 (see fig. on page 73)

Target

  • heat dissipation (water cooling)
  • electrical isolation and contacts (cooling water lines at high voltages!)
  • ground shielding (to prevent sputtering from target construction elements)
  • construction materials: Stainless steel, copper, aluminum (corrodes in water!)

 

Power supply

  • dc source

output power depends on the target size. It should be capable of delivering 10W/cm2 at voltage up to 5kV (this does not apply to magnetron sputtering which requires higher currents at lower voltages)

  • rf source

Set to one of the ISM (Industrial-Scientific-Medical) allocated frequencies. For the ISM frequencies there is no limit on the radiated power. The often used ISM frequencies are: 13.56 MHz, 27.12 MHz, and 40.68 MHz
Output impedance of rf generators is usually 50W while that of the glow discharge is much higher - matching network needed. We employ the solutions known from radio emitting generators matching to the station antenna. Matching circuitry is located close to the target assembly.

Solution for a single ended sputtering:

Insert figure p.74

For bias sputtering power splitters are needed.

 Power regulating and matching is done by variable coupling:

(see fig. on page 74)

Instrumentation and control

Parameters to monitor:

  • dc voltage
  • dc current
  • power (in rf systems)
  • pressure

In rf systems control also the matching by means of

  • SWR meters
  • Power split ratio
  • Self bias meter

Film specific parameters:

  • Substrate temperature
  • Thickness and rate of deposition

Scale-up problems

 

From a lab system to a large industrial plant.
Each application must be treated as a special case.

Preparation and preconditioning of targets, substrates and systems for deposition.

Targets

  • bonding the target to the electrode
  • presputtering (no change of sputter conditions are allowed afterwards)
  • target errosion problems

Substrate – sputter etch cleaning

  • organic contamination – best sputter in O2
  • contamination of the target while sputtering onto the shutter: use “catcher” shutters when cleaning the substrate

Sputter gas

Work horse of the sputtering systems – Argon. Maintain constant flow and pumping to remove contamination and to operate in a pure gas. Argon purifiers: Palladium filter.

Getter sputtering
To reduce the amount of background contamination, presputter on a cooled cylinder enclosing the target, and only later open the shutter. Example: Nb, Ti,  superconducting films.

Reactive sputtering:
Sputter in an active gas to obtain chemical  modification of the target material.

  • Sputtering in air (O2, H2O) – oxides
  • Sputtering in N2, NH3 – nitrides
  • Sputtering in O2 + N2 – oxynitrides
  • Sputtering in H2S – sulfides
  • Sputtering in C2H2, CH4 – carbides
  • Sputtering in SiH4 - silicides, etc…

Bias sputtering

Any material body immersed in a glow discharge acquires (when not grounded) a floating potential which is slightly negative with respect to the ground. Floating potential results from the difference in mobility of electrons and ions, and can be shown to be
thin films
Where m and Te stands for electron mass and electron temperature, respectively, M is the ion mass.

The substrate in glow discharge may be treated as floating plane Langumir probe of a characteristics:
(see fig. on page 78)

At the point Vp the probe is at the same potential as the plasma (plasma potential is
thin films
Where Ti and qi are the temperature and charge of the involved ions. The equations for Vp and Vf are drown in the approximation of no magnetic field and they can be used to evaluate Ti and Te.

N.B. If the substrate is dielectric and the holder is grounded then the substrate will be at Vs and the holder at Vs-Vf. In consequence there will be non-uniform bombardment resulting in variable thickness and composition. Good rule is “Do not ground the substrate”.

To protect deposited films or to modify their properties – biased deposition. Positive bias results in large electron current, hence heating. Negative bias enables ion implantation - e.g., deposition of TiN.

Magnetron Sputtering

Limitations of conventional sputtering:

  • yield (rate of deposition)
  • pressure limits (the yield is high between 50 to 150 mTorr, see graph p 80)
  • high voltage requirement

The magnetron sputtering principle: magnetic field is used in concert with the cathode surface to form electron traps that are so configured that E x B electron drift currents close on themselves. This method is used also in microwave generators, also named magnetron. The method can work both with dc and rf, at different configurations hollow, cylindrical, planar, or gun. (see fig 22 d,e)

Magnetron sputtering

Classical sputtering

 

V – 800 V
B – 150 G
p – 1 mTr
J – 20mA/cm2
r (Ar,Ni)– 2000 A/s (at the target 12000 A/s)
No plasma bombardment of the substrate

V – 3 kV
dca - 4 to 5 cm
p – 75 mTr
J – 1mA/cm2
r (Ar,Ni) – 360 A/s
Substrate exposed to plasma

Magnetron source is the best high rate source can be used in planar, circular or rectangular configuration (Fig. 23b).

Problems: erosion profile – max usage of the target volume up to 20% only. Solution: Patents by Sloan and Varian, the Sputter gun and the S-gun (Fig. 23 e,f)

Technical problems:

  • The need for small and very strong magnets – almico alloys from the rare earth ferrites. Magnetron magnets have to work in an “open” configuration and high coercion is required – no loss of magnetic field is allowed (Fig. 23c).
  • Isolation, cooling, and cathode shielding (O’ ring protection) Fig. 23d.

Some amazing historical remarks comments:

  • US patent 1939 Penning (for a magnetron principle ion pump)
  • 1939/40 microwave magnetron source for cm-wave radar
  • the first time used for deposition 1969 (!) Meissel
  • deposition patent 1974
  • commercially available 1975
  • full version (rf + bias) 1976

Ion Beam Deposition

Primary/Direct:
thin films
ion beam consists of the desired materials and is deposited at low energy (around 100 ev) directly onto the substrate.
Secondary

Ion sources

Penning (Fig. 23e)
The opened cathode acts also as an extractor. The spread of ion energies is 10 - 50 eV.

Kaufman (Fig. 23f)
This is an extension of the Penning concept, which includes a thermionic cathode and a proper extractor. Heated cathode allows operation at low pressures and voltages (50V). The spread of the ion energy is 1 – 10 eV. Control the emission rate by controlling the electron emission rate. Output grid – double-screen grid (~1400 holes of 0.21 mm diameter within the 10 cm dia) + accelerator grid. Density of Ar ions from a 10 cm source: 1 – 2 mA/cm2 at a beam energy of 500 – 2000 ev. Ionization efficiency ~ 75%.

Duplasmatron (Fig. 23g)
For high intensity, narrow beams. The name reflects the dual manner of constricting the plasma in an arc discharge by both electric and magnetic fields.
The filament supports 1-2A arc between the anode and the cathode (80V discharge voltage). There is “in between” electrode “Zwischen” cathode at the intermediate potential of 40V. The canal-shaped aperture in this electrode confines the discharge electrically and 0.1 – 0.3 T magnetic field between the Zwischen electrode and the anode constrains the plasma axially.
The diverging magnetic field region shapes a plasma meniscus next in the anode aperture (Fig. 22h) which becomes the emitting surface for ion extraction.
Ar ion currents above 2 mA are obtained at about 20 keV beam energy through 300 mm dia aperture with the energy spread of 10 – 50 eV.

BEAM EXTRACTION AND CONTROL

 

Ion extraction

Ions in the plasma diffuse to the boundary where they can get extracted by an electric field and form a proper beam. The rate of extraction:
Child’s low of space charge limited current flow (as in a vacuum diode valve). For planer geometry – two planes at a distance d and voltage V

thin films

This is the upper limit for any particle source. The determining factors are the voltage and the electrode spacing.
For non-planar geometries the proportionality constant changes. It can be determined from the j/V3/2 ratio.
Typically one has the extraction electrode at the ground potential and the entire source at high V.
The plasma meniscus adjusts itself to satisfy the Child’s low at the local electric field. Fig. 23i shows normal extraction conditions and 23j shows excessive ion production resulting in the loss of the beam collimation.

System requirements:

  • materials: the cathode filaments and electrode apertures - sources of contamination. Grids optimum material - molybdenum. Small distance between the grids – problems associated with their thermal expansion.
  • lifetime of the source: hot cathode burning out or buildup of the sputtered material in the source. Typical lifetimes range from hours to months.
  • vacuum and gas
  • power supplies

Secondary ion deposition equipment

Veeco system with the 8 cm Kaufmen source, fig. 24a.
Beam diameter 7 cm, target dia. 13 cm, ion energy 200:2000 eV, beam current 30 mA.
Position 1: target presputter
Position 2: substrate precleaning
Position 3: deposition

Duplasmatron source with Einzel lens - General Louex Corp. USA. Fig. 24b:
20 keV Ar ions in 4 mm beam enables operation from very small targets, down to mg amounts of the sputtered material.

Reactive ion beam sputtering
possible configurations  (insert  fig. on page 87)

Primary ion beam deposition
e.g. diamond films by means of a Penning source with carbon electrodes and Argon gas.  The beam consists of C ions, C neutrals, Ar ions and neutrals. (see fig. on page 88)

Chemical methods

Typically deposition from solutions, the most popular aqueous solutions.

Deposition by a chemical reaction
e.g. Ag films for silver mirrors:
Solution of silver salt (usually AgNO3) in one solution and a reducing agent in the second solution. Two solutions are sprayed on the surface that has been "sensitized", e.g. by dipping in a solution of SnCl2 acidified with HCl.

Most common deposits Cu, Ag, Au, PbS (for coloring brass), and Ni. Deposition also on non-conduction surfaces.

Autocatalytic chemical reduction (“electroless plating”)

Deposition of a metallic coating by a controlled chemical reaction catalyzed by the metal or the alloy being deposited
( Mn+ + ne -> M0 ) only on catalytic surfaces

After the initiation of the reaction it becomes self-sustaining.

Example, Ni:
2H2PO2 + 2H2O + Ni2+ z Ni0 + H2 + 4H+ + 2HPO32-
The reaction goes as follows:
HPO2 + H2O (cat.zsurf.) HPO3- + 2H+ + H-
2H- + Ni2+ z Ni0 + H2
The efficiency may be decreased by a spurious reaction H+ + H- z H2.
Possible catalytic surface: Ni, Co, Rh, Pd, steel…Non-catalytic surface can be activated simply by touching with a catalytic agent.

Typical electroless deposits: Ni, Co, Pd, Pt, Cn, Au, Ag.

Conversion coating

  • Oxides
  • Chromates
  • Phosphates

Displacement deposition ("immersion plating")
Used more for recovery of the metal than for the actual plating. Known also as “cementation”.

Electro-deposition by electrochemical reactions

Faraday's laws (1833):

  • The amounts of chemical charge produce by the current is proportional to the quantity of electricity that passes
  • The amounts of different substances liberated by a given quantity of electricity are proportional to their electrochemical equivalent weights

Electrochemical equivalent weight :

thin films

For example, if Fe is being deposited from Fe2+ solution (valence change 2), e=55.85/2=27.93.
If Fe3+ would be used,  then e=18.62.

N.B. an old definition of Coulomb unit: ! C is the amounts of electricity that deposits 0.001118 g of Ag from a solution.

It follows from the Faraday's law that the amounts of electricity needed to deposit 1 g electrochemical equivalent weight of any element is one Faraday
thin films
The mass of the reacting substance is
thin films
where G is mass in [g], I is current in [A], e is elect. eq. weight and t is time [s].

Important factors is electroplating

  • pH
  • J
  • T
  • agitation
  • bath composition

 

Chemical Vapor Deposition ("CVD")

Reaction from the gas phase to form solid on the surface. There are many types of reaction:

  1. Pyrolisis,

SiH4(g) z Si(s) + 2H2(g)

  1. Reduction,

SiCl4(g) + 2H2(g) z Si(s) + 4HCl(g)

  1. Oxidation,

SiH4(g) + O2(g) zSiO2(s) + 2H2(g)

  1. Hydrolysis,

Al2Cl6(g) + 3CO2(g) + H2(g) z Al2O3(s) + 3HCl(g) + 3CO(g)

  1. Nitride formation,

3SiH4(g) + 4NH3(g) z Si3N4(s) + 12H2(g)

  1. Carbide formation,

TiCl4(g) + CH4(g) zTiC(s) + 4HCl(g)

  1. Disproportionation,

2GeI2(g) (lower temp) z Ge(s) + GeI4(g)

  1. Synthesis,

(CH3)3Ga(g) + AsH3(g) z GaAs(s) + 3CH4(g)

  1. Chemical transport,

6GaAs(g) + 6HCl(g) F As4(g) + As2(g) + GaCl(g) + 3H2(s)

The reaction goes forward at high temperature and backwards at lower. Lowering the temperature in the down-stream part of the reactor initiates the deposition of GaAs(s)

  1. All possible combinations of the above reactions.

 

Thermodynamics for calculating temperature of reaction and optimizing the chemistry. Kinetics of the reaction - all processes determine the rate.

High pressure and low pressure CVD

  • High pressure  - fig 24 c
  • Normal pressure – flow CVD – fig 24 d
  • Low pressure, vacuum CXVD fig 24 e.

 

types of CVD reactors: examples: 24f pedestal, 24g horizontal, 24h barrel and 24j pancake
Fig 25 a – epitaxial GaAs CVD

Physical-chemical methods.

  • plasma deposition
  • polymerization
  • plasma spraying.

Nucleation and growth of thin films

Film growth stages:

  1. Nucleation 25 c
  2. Nucleus growth
  3. Coalescence 25 b

The growth kinetics, which determines the structure, texture and the state of the film surface, depends on the deposition rate and the substrate temperature.

The mechanism of condensation:
V – L – S, when the substrate is hot
V – L,  when the substrate is at low temperature T<Tm/3, see 25 d, e.
Films quenched at very low temperatures have amorphous structure. This is the way to achieve metallic glasses.

Pattern definition

  • Master mask fabrication
  • coordinate table
  • digital techniques
  • Photoreduction (two stages: X 10 and X 30)
  • Chromium working maskes

 

Photoresists.
Negative photoresists (Fig 26a):

  • KMER - Kodak metal etch
  • KPR    - Kodak photo-resist
  • KTFR  - Kodak thin film
  • KPL    - Kodak photo-resistive lacquer

Resolution increases from a) to d). Chemical resistance increases from d) to a

Positive photoresists.
AZ 1350
AZ 1350 H (hard)
AZ 1350 J (electron sensitive resist)

Photoresit processing:

  • Spinning
  • Drying – sensitive.
  • Exposing
  • Developing
  • Rinsing
  • Drying
  • Hardening

Lift-off techniques

Fig 26 b,c,d.  Projection exposure through the transparent substrate to avoid undercuts (fig. 26e)

Equipment

(Carl Suss - Switzerland)
Exposition and mask aligner (Fig. 27a)
Substrate table (Fig. 27b) and table movement system (Fig. 27c)
Infrared alignment (Fig. 27d)
Laser alignment and exposition (Fig. 27e,f)

Etching process

  • Chemical
  • Plasma
  • Ion
  • Reactive
  • Reactive ion etch

 

“undercut” issue

 

thin films

Thickness measurements

Optical methods

  • Optical - interferometry (on the step edge (Fig. 28a,b))

thin films

Where N is the order, n is the refraction index of the film and d is thickness. Opaque films needs a step in the thickness down to the substrate.

  • Fringes of the equal thickness - Fizeau
  • Fringes of equal chromatic order (parallel plate but white and non-monochromatic light) - watch for minimum as a function of the wavelength.
  • Optical VAMFO - variable angle monochromatic fringe observation.
  • Elipsometry (Fig. 28c) - measure relative amplitudes and phase of parallel and perpendicular components.

Non-optical methods

  • Stylus - down to 10Å Computer aided. Dektac, Alphastep, etc

thin films(Fig. 28d).

  • Precision weight - mass measurement (Fig. 28e,f). Quartz weight – needs calibration for a given system-source-substrate arrangment (Z-factor)
  • X-ray fluorescence (compare intensity with standards)
  • b Scattering - as c) but much simpler (Fig. 28g)

 

 

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